SYNTHESIS OF ION-EXCHANGE RESINS
Keywords:
ion-exchange, gel, volumetric exchange capacity, degree of swelling, phenol-formaldehyde oligomer, modification, sulfocationiteAbstract
Ion-exchange resins are insoluble, high-molecular compounds that contain functional ionogenic groups capable of participating in ion-exchange reactions with ions in solution. Some types of ion-exchangers also possess complexation capabilities, redox reactivity, and the physical ability to adsorb various compounds.
Ion-exchangers can have gel-type, porous, or intermediate structures. Gel-type ion-exchangers lack porosity and exhibit ion-exchange capacity only when swollen. In contrast, porous ion-exchangers have a well-developed surface due to their porosity, enabling ion-exchange in both swollen and unswollen states. While gel-type ion-exchangers typically possess higher exchange capacities, they are generally inferior to porous ones in terms of osmotic stability, chemical resistance, and thermal durability.
Ion-exchange resins find extensive applications in industrial water purification, removal of heavy metals, and in diverse sectors such as chemistry, energy, metallurgy, pharmaceuticals, and food processing.
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